Chae Changwon, Hong Jiseok, Kim Hyunjung, Kim Dong Hyun, Lee Seung Oh, Kim Ijung
Department of Civil and Environmental Engineering, Hongik University Seoul 04066 Republic of Korea
RSC Adv. 2025 Aug 19;15(36):29190-29200. doi: 10.1039/d5ra03653d. eCollection 2025 Aug 18.
Synthetic surfactants have been associated with environmental concerns, requiring their replacement with natural alternatives such as saponins. In this study, saponin extraction from soapnut was optimized using the reflux method through the Box-Behnken design and response surface methodology (RSM). Foams generated from the saponin solution were evaluated for effectiveness in ammonia and particulate matter (PM) removal, along with foam characteristic analysis. The optimized saponin extraction yielded 30.18% saponin, exceeding the yields achieved through conventional methods. The extracted saponin exhibited enhanced foamability with increasing concentrations, leading to an expanded surface area that facilitated the removal ammonia and PM removal through foam-based adsorption. Ammonia removal was further improved as the foamability and stability of surfactant foams increased at saponin concentrations above the critical micelle concentration (CMC) under neutral pH conditions. The comparable PM removal efficiency of saponin-based foams to that of synthetic surfactants underscores their potential as an effective and environmentally sustainable solution for air pollution control.
合成表面活性剂已引发环境问题,需要用天然替代品如皂苷来取代它们。在本研究中,通过Box-Behnken设计和响应面方法(RSM),采用回流法优化了从无患子中提取皂苷的工艺。对皂苷溶液产生的泡沫进行了氨和颗粒物(PM)去除效果评估以及泡沫特性分析。优化后的皂苷提取率为30.18%,超过了传统方法的提取率。提取的皂苷随着浓度增加表现出增强的发泡性,导致表面积扩大,有利于通过基于泡沫的吸附去除氨和PM。在中性pH条件下,当皂苷浓度高于临界胶束浓度(CMC)时,表面活性剂泡沫的发泡性和稳定性增加,氨去除效果进一步提高。基于皂苷的泡沫与合成表面活性剂的PM去除效率相当,这突出了它们作为空气污染控制的有效且环境可持续解决方案的潜力。