Could Fostering Alternative Plant Feedstocks Improve the Sustainability of Leather Manufacturing? A Critical Review.

Vegetable tannins (VTs) are natural polyphenolic compounds widely used in leather tanning as sustainable alternatives to chrome-based processes. Traditionally, only a limited number of commercially available tannins, such as mimosa, quebracho, and chestnut, are employed globally, often requiring long-distance transportation with associated environmental and economic costs. This review systematically explores recent advances (2015-2025) in the identification and evaluation of alternative VT sources derived from underutilized plant species in Africa and Asia. Chemical composition, extraction efficiency, and tanning performance, including hydrothermal stability, tensile strength (TS), elongation at break (EB%), and tear strength (Ts), are critically analyzed and compared with conventional agents. Particular focus is given to the tannin/non-tannin ratio (T/N), a key indicator of tanning potential. Promising results were found for extracts from , , , , and . Preliminary environmental assessments (COD, BOD, TDS) also suggest comparable impacts to standard tannins. However, performance variability due to species, plant part, seasonality, and extraction conditions remains a challenge. This review underscores the potential of regionally sourced VTs to support proximity-based economies and reduce the environmental footprint of the leather industry, while highlighting the need for further studies to optimize extraction protocols and scale industrial application.