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1
White lines in L-edge x-ray absorption spectra and their implications for anomalous diffraction studies of biological materials.L 边 X 射线吸收光谱中的白线及其对生物材料反常衍射研究的意义。
Proc Natl Acad Sci U S A. 1980 Oct;77(10):5884-8. doi: 10.1073/pnas.77.10.5884.
2
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3
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4
Contemporary Use of Anomalous Diffraction in Biomolecular Structure Analysis.反常衍射在生物分子结构分析中的当代应用
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X-ray spectroscopy and X-ray diffraction at wavelengths near the K-absorption edge of phosphorus.在磷的K吸收边附近波长处的X射线光谱学和X射线衍射
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7
Feasibility and review of anomalous X-ray diffraction at long wavelengths in materials research and protein crystallography.材料研究和蛋白质晶体学中长波长异常X射线衍射的可行性及综述。
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Anomalous Dispersion with Edges in the Soft X-ray Region: First Results of Diffraction from Single Crystals of Trypsin Near the K-Absorption Edge of Sulfur.软X射线区域中带边缘的反常色散：胰蛋白酶单晶在硫的K吸收边附近衍射的初步结果。
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Effect of the anisotropy of anomalous scattering on the MAD phasing method.反常散射的各向异性对多波长反常散射（MAD）相位法的影响。
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Thiol-reactive lanthanide chelates for phasing protein X-ray diffraction data.用于蛋白质X射线衍射数据相位分析的硫醇反应性镧系螯合物。
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1
Facing the phase problem.面对相移问题。
IUCrJ. 2023 Sep 1;10(Pt 5):521-543. doi: 10.1107/S2052252523006449.
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Anomalous diffraction in crystallographic phase evaluation.晶体相评估中的异常衍射。
Q Rev Biophys. 2014 Feb;47(1):49-93. doi: 10.1017/S0033583514000018.
3
Multiwavelength anomalous diffraction analysis at the M absorption edges of uranium.铀的M吸收边处的多波长反常衍射分析
Proc Natl Acad Sci U S A. 2001 Sep 11;98(19):10648-53. doi: 10.1073/pnas.191003998. Epub 2001 Aug 28.
4
Configuration of the four iron atoms in dissolved human hemoglobin as studied by anomalous dispersion.通过反常色散研究溶解的人血红蛋白中四个铁原子的构型。
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5
Anomalous x-ray scattering from terbium-labeled parvalbumin in solution.溶液中铽标记的小白蛋白的反常X射线散射。
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本文引用的文献

1
LIII-Edge Anomalous X-ray Scattering by Cesium Measured with Synchrotron Radiation.用同步辐射测量铯的LIII边反常X射线散射
Science. 1978 Jul 21;201(4352):257-9. doi: 10.1126/science.201.4352.257.
2
Determination of the distance between heavy-atom markers in haemoglobin and histidine decarboxylase in solution by small-angle x-ray scattering.通过小角X射线散射测定溶液中血红蛋白和组氨酸脱羧酶中重原子标记物之间的距离。
FEBS Lett. 1980 Jul 11;116(1):107-10. doi: 10.1016/0014-5793(80)80539-4.
3
High affinity calcium binding sites on erythrocyte membrane proteins. Use of lanthanides as fluorescent probes.红细胞膜蛋白上的高亲和力钙结合位点。镧系元素作为荧光探针的应用。
Biochim Biophys Acta. 1974 Sep 6;363(2):211-8. doi: 10.1016/0005-2736(74)90060-1.
4
Applications of synchrotron radiation to protein crystallography: preliminary results.同步辐射在蛋白质晶体学中的应用：初步结果。
Proc Natl Acad Sci U S A. 1976 Jan;73(1):128-32. doi: 10.1073/pnas.73.1.128.
5
Asymmetric structure of the purple membrane.紫膜的不对称结构。
Science. 1977 Jun 3;196(4294):1101-4. doi: 10.1126/science.870970.
6
Dependence of the conformation of the polar head groups of phosphatidylcholine on its packing in bilayers. Nuclear magnetic resonance studies on the effect of the binding of lanthanide ions.磷脂酰胆碱极性头部基团的构象对其在双层膜中堆积的依赖性。镧系离子结合效应的核磁共振研究。
Biochemistry. 1979 Sep 18;18(19):4169-72. doi: 10.1021/bi00586a019.
7
Structure determination of asymmetric membrane profiles using an iterative Fourier method.使用迭代傅里叶方法确定不对称膜轮廓的结构
Biophys J. 1979 Mar;25(3):495-512. doi: 10.1016/S0006-3495(79)85319-9.
8
Helical channels in crystals of gramicidin A and of a cesium--gramicidin A complex: an x-ray diffraction study.短杆菌肽A晶体及铯-短杆菌肽A复合物晶体中的螺旋通道：X射线衍射研究
J Mol Biol. 1978 May 5;121(1):41-54. doi: 10.1016/0022-2836(78)90261-9.

L 边 X 射线吸收光谱中的白线及其对生物材料反常衍射研究的意义。

White lines in L-edge x-ray absorption spectra and their implications for anomalous diffraction studies of biological materials.

作者信息

Lye R C, Phillips J C, Kaplan D, Doniach S, Hodgson K O

出版信息

Proc Natl Acad Sci U S A. 1980 Oct;77(10):5884-8. doi: 10.1073/pnas.77.10.5884.

DOI:10.1073/pnas.77.10.5884
PMID:6934520
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC350176/
Abstract

We have measured high-resolution x-ray absorption spectra of lanthanide (Ln) and heavy transition metal complexes that display prominent narrow absorption peaks near the L2 and L3 absorption edges. The anomalous scattering factors (f' and f"), which are mathematically related to the absorption cross section, have correspondingly sharp changes in their magnitude within 5-10 eV of the absorption edge. Calculations of the magnitude of the change in f' and f" demonstrate that significant changes (on the order of 20 electrons in f') can be expected for these materials. These substantial changes in the anomalous scattering factors have applications to deriving structural information for macromolecules from x-ray diffraction studies. The magnitude of the changes indicate that the anomalous scattering technique is a powerful means of obtaining structural characteristics for macromolecules in single crystals, in solution, and in biological membranes.

摘要

我们测量了镧系元素（Ln）和重过渡金属配合物的高分辨率X射线吸收光谱，这些配合物在L2和L3吸收边附近显示出突出的窄吸收峰。与吸收截面数学相关的反常散射因子（f'和f"）在吸收边的5-10 eV范围内其大小相应地有急剧变化。对f'和f"变化幅度的计算表明，这些材料有望出现显著变化（f'变化约20个电子）。反常散射因子的这些显著变化可应用于从X射线衍射研究中推导大分子的结构信息。变化幅度表明，反常散射技术是获取单晶、溶液和生物膜中大分子结构特征的有力手段。