Chou K C, Li T T, Forsén S
Biophys Chem. 1980 Dec;12(3-4):265-9. doi: 10.1016/0301-4622(80)80003-2.
As we go more deeply into the theoretical analysis and actual calculations for enzymatic fast reaction systems, the concept of the critical shell would naturally be confronted with. In this paper, a formula is presented to estimate the thickness of the critical shell. An on such a basis, we have made calculations and discussed the influences of various factors such as short-range force, long-range force, activation energy and cavity-active site upon the thickness of the critical spherical shell.
随着我们对酶促快速反应体系的理论分析和实际计算的深入，必然会遇到临界壳层的概念。本文提出了一个估算临界壳层厚度的公式。在此基础上，我们进行了计算，并讨论了短程力、长程力、活化能和空穴-活性位点等各种因素对临界球壳厚度的影响。
