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山金车地上部分的三萜皂苷。

Triterpenoid saponins from the aerial parts of Aster bellidiastrum.

作者信息

Schöpke T, al-Tawaha C, Wray V, Nimtz M, Meyer A, Hiller K

机构信息

Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät I, Institut für Pharmazie, Germany.

出版信息

Phytochemistry. 1995 Nov;40(5):1489-92. doi: 10.1016/0031-9422(95)00432-7.

Abstract

Four major triterpenoid saponins were isolated from the aerial parts of Aster bellidiastrum. The structures were elucidated from their NMR and mass spectral data, and from derivatization. One is a new compound with the structure 3-O-beta-D-glucopyranosyl-2 beta,3 beta,16 alpha,23-tetrahydroxyolean-12-en-28- oic acid 28-O-beta-D-xylopyranosyl(1-->4)-alpha-L-rhamnopyranosyl(1-->2)-beta- D-fucopyranoside, while the three others have been previously identified in extracts from various Bellis species.

摘要

从山金车地上部分分离出四种主要的三萜皂苷。通过核磁共振(NMR)和质谱数据以及衍生化确定了它们的结构。其中一种是新化合物,结构为3 - O - β - D - 吡喃葡萄糖基 - 2β,3β,16α,23 - 四羟基齐墩果 - 12 - 烯 - 28 - 酸28 - O - β - D - 吡喃木糖基(1→4) - α - L - 鼠李吡喃糖基(1→2) - β - D - 岩藻吡喃糖苷,而另外三种先前已在各种雏菊属植物提取物中鉴定出。

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