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氚核磁共振波谱法。一些氚标记类固醇的分布模式和核Overhauser效应增强

Tritium nuclear magnetic resonance spectroscopy. Distribution patterns and nuclear Overhauser enhancements in some tritiated steroids.

作者信息

Altman L J, Silberman N

出版信息

Steroids. 1977 Apr;29(4):557-65. doi: 10.1016/0039-128x(77)90074-5.

DOI:10.1016/0039-128x(77)90074-5
PMID:867452
Abstract

The distribution of tritium atoms in some labeled steroids has been determined by tritium nuclear magnetic resonance spectroscopy. In addition, the distribution of molecular types (mono vs. polytritiated) and nuclear Overhauser enhancements have been determined. As near maximal NOE's were observed, quantitative distribution information was derived from NOE suppressed spectra.

摘要

通过氚核磁共振光谱法已确定了一些标记类固醇中氚原子的分布。此外,还确定了分子类型(单氚化与多氚化)的分布以及核Overhauser增强效应。由于观察到了近乎最大的核Overhauser增强效应,因此从核Overhauser增强效应抑制光谱中获得了定量分布信息。

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