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傅里叶变换离子回旋共振(FT-ICR)光谱学的早期发展。

The early development of Fourier transform ion cyclotron resonance (FT-ICR) spectroscopy.

作者信息

Comisarow M B, Marshall A G

机构信息

Department of Chemistry, University of British Columbia, Vancouver, Canada.

出版信息

J Mass Spectrom. 1996 Jun;31(6):581-5. doi: 10.1002/(SICI)1096-9888(199606)31:6<581::AID-JMS369>3.0.CO;2-1.

Abstract

The development of Fourier transform ion cyclotron resonance (FT-ICR) spectroscopy is traced from its 1973 conception by analogy to Fourier transform nuclear magnetic resonance (FT-NMR) spectroscopy and its 1974 experimental demonstration to its 1978 demonstration as the technique of choice for examining complex ion chemistry. The intellectual connections between conventional NMR and ICR and FT-NMR are described. The theoretical prediction and experimental demonstration of the many advantageous features of FT-ICR are described. Subsequent FT-ICR technique developments and applications are mentioned briefly.

摘要

傅里叶变换离子回旋共振(FT - ICR)光谱学的发展历程可追溯到1973年,当时它是通过类比傅里叶变换核磁共振(FT - NMR)光谱学构想出来的,并于1974年进行了实验演示,到1978年已成为用于研究复杂离子化学的首选技术。文中描述了传统核磁共振与离子回旋共振以及傅里叶变换核磁共振之间的知识联系。阐述了傅里叶变换离子回旋共振诸多优势特性的理论预测和实验演示。随后简要提及了傅里叶变换离子回旋共振技术的后续发展及应用。

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