紫外光引导下分离新型青霉生物碱阿兰替哌酮
UV-Guided isolation of alantrypinone, a novel Penicillium alkaloid.
作者信息
Larsen T O, Frydenvang K, Frisvad J C, Christophersen C
机构信息
Mycology Group, Department of Biotechnology, Technical University of Denmark, DK-2800 Lyngby, Denmark.
出版信息
J Nat Prod. 1998 Sep;61(9):1154-7. doi: 10.1021/np980056v.
PMID:9748389
Abstract
Fumiquinazoline F (1) and alantrypinone (2) have been isolated as the two major metabolites of Penicillium thymicola. The structure of 2, which contains a new ring structure, was elucidated by analysis of spectroscopic data including 2D NMR. The absolute configuration of 2 was established by a single-crystal X-ray diffraction study.
摘要
烟曲霉喹唑啉F（1）和丙氨酸（2）已被分离为胸腺青霉的两种主要代谢产物。通过包括二维核磁共振在内的光谱数据分析，阐明了含有新环结构的2的结构。通过单晶X射线衍射研究确定了2的绝对构型。
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