• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

通过透射光栅衍射测定氦二聚体的键长和结合能。

Determination of the bond length and binding energy of the helium dimer by diffraction from a transmission grating.

作者信息

Grisenti RE, Schollkopf W, Toennies JP, Hegerfeldt GC, Kohler T, Stoll M

机构信息

Max-Planck-Institut fur Stromungsforschung, Bunsenstrasse 10, 37073 Gottingen, Germany.

出版信息

Phys Rev Lett. 2000 Sep 11;85(11):2284-7. doi: 10.1103/PhysRevLett.85.2284.

DOI:10.1103/PhysRevLett.85.2284
PMID:10977992
Abstract

A molecular beam consisting of small helium clusters is diffracted from a 100 nm period transmission grating. The relative dimer intensities have been measured out to the 7th order and are used to determine the reduction of the effective slit width resulting from the finite size of the dimer. From a theoretical analysis of the data which also takes into account the van der Waals interaction with the grating bars, the bond length (mean internuclear distance) and the binding energy are found to be = 52+/-4 A and |E(b)| = 1. 1+0.3/-0.2 mK.

摘要

一束由小氦团簇组成的分子束从一个周期为100纳米的透射光栅发生衍射。已测量出相对二聚体强度直至七阶,并用于确定由于二聚体的有限尺寸导致的有效狭缝宽度的减小。通过对数据的理论分析,其中还考虑了与光栅条的范德华相互作用,发现键长(平均核间距)和结合能分别为 = 52±4 Å和|E(b)| = 1.1 +0.3/-0.2 mK。

相似文献

1
Determination of the bond length and binding energy of the helium dimer by diffraction from a transmission grating.通过透射光栅衍射测定氦二聚体的键长和结合能。
Phys Rev Lett. 2000 Sep 11;85(11):2284-7. doi: 10.1103/PhysRevLett.85.2284.
2
Matter wave diffraction from an inclined transmission grating: searching for the elusive 4He trimer Efimov state.倾斜透射光栅的物质波衍射:寻找难以捉摸的4He三聚体埃菲莫夫态。
Phys Rev Lett. 2005 Aug 5;95(6):063002. doi: 10.1103/PhysRevLett.95.063002. Epub 2005 Aug 2.
3
Pair potential for helium from symmetry-adapted perturbation theory calculations and from supermolecular data.基于对称适配微扰理论计算和超分子数据的氦的对势
J Chem Phys. 2007 Sep 28;127(12):124303. doi: 10.1063/1.2770721.
4
Evidence for a bound HeH2 halo molecule by diffraction from a transmission grating.通过透射光栅衍射获得的关于束缚态HeH₂ 晕分子的证据。
J Chem Phys. 2004 Jul 8;121(2):625-7. doi: 10.1063/1.1768935.
5
Analysis and observation of finite beam Bragg diffraction by a thick planar phase grating.
Appl Opt. 1996 Feb 1;35(4):582-92. doi: 10.1364/AO.35.000582.
6
Bounds for the scattering length of spin-polarized helium from high-accuracy electronic structure calculations.基于高精度电子结构计算的自旋极化氦散射长度的界限
J Chem Phys. 2005 Oct 1;123(13):134315. doi: 10.1063/1.2042453.
7
Quantum reflection of He2 several nanometers above a grating surface.氦-2 几纳米上方光栅表面的量子反射。
Science. 2011 Feb 18;331(6019):892-4. doi: 10.1126/science.1200911.
8
Measuring concave diffraction grating efficiencies at grazing incidence.掠入射时凹面衍射光栅效率的测量。
Appl Opt. 1977 Dec 1;16(12):3171-5. doi: 10.1364/AO.16.003171.
9
Nondestructive mass selection of small van der waals clusters.非破坏性的范德瓦尔斯小团簇的质量选择。
Science. 1994 Nov 25;266(5189):1345-8. doi: 10.1126/science.266.5189.1345.
10
Nuclear spin-spin coupling in a van der Waals-bonded system: xenon dimer.范德华键合体系中的核自旋-自旋耦合:氙二聚体。
J Chem Phys. 2013 Mar 14;138(10):104313. doi: 10.1063/1.4793745.

引用本文的文献

1
Rydberg Macrodimers: Diatomic Molecules on the Micrometer Scale.里德伯巨二聚体:微米尺度的双原子分子。
J Phys Chem A. 2023 May 11;127(18):3925-3939. doi: 10.1021/acs.jpca.2c08454. Epub 2023 Mar 28.
2
Topologically-imposed vacancies and mobile solid He on carbon nanotube.碳纳米管上的拓扑诱导空位与可移动固态氦
Nat Commun. 2022 Oct 5;13(1):5873. doi: 10.1038/s41467-022-33539-8.
3
Fully quantum calculation of the second and third virial coefficients of water and its isotopologues from ab initio potentials.基于从头算势能对水及其同位素变体的第二和第三维里系数进行全量子计算。
Faraday Discuss. 2018 Dec 13;212(0):467-497. doi: 10.1039/c8fd00092a.
4
Pendular alignment and strong chemical binding are induced in helium dimer molecules by intense laser fields.强激光场诱导氦二聚体分子产生摆动对齐和强化学键。
Proc Natl Acad Sci U S A. 2018 Sep 25;115(39):E9058-E9066. doi: 10.1073/pnas.1810102115. Epub 2018 Sep 7.
5
Photocatalytic degradation of dimethoate in Bok choy using cerium-doped nano titanium dioxide.利用掺铈纳米二氧化钛对白菜中乐果的光催化降解。
PLoS One. 2018 May 17;13(5):e0197560. doi: 10.1371/journal.pone.0197560. eCollection 2018.
6
Imaging the He2 quantum halo state using a free electron laser.利用自由电子激光对氦-2量子晕态进行成像。
Proc Natl Acad Sci U S A. 2016 Dec 20;113(51):14651-14655. doi: 10.1073/pnas.1610688113. Epub 2016 Dec 6.
7
Formation of dimers of light noble atoms under encapsulation within fullerene's voids.在富勒烯空隙内封装情况下轻稀有原子二聚体的形成。
Nanoscale Res Lett. 2015 Apr 17;10:185. doi: 10.1186/s11671-015-0871-x. eCollection 2015.
8
Alternative analytical forms to model diatomic systems based on the deformed exponential function.基于变形指数函数对双原子系统进行建模的替代分析形式。
J Mol Model. 2014 Jul;20(7):2297. doi: 10.1007/s00894-014-2297-2. Epub 2014 Jun 18.
9
Comparison of some dispersion-corrected and traditional functionals with CCSD(T) and MP2 ab initio methods: dispersion, induction, and basis set superposition error.比较一些经分散修正和传统泛函与 CCSD(T)和 MP2 从头算方法:分散、诱导和基组超交误差。
J Chem Phys. 2012 Oct 7;137(13):134109. doi: 10.1063/1.4755990.