Saarinen L, Hakkola M, Kangas J
Finnish Institute of Occupational Health, Topeliuksenkatu 41a, FIN-00250 Helsinki, Finland.
J Environ Monit. 2000 Dec;2(6):662-5. doi: 10.1039/b005599i.
The purpose of this study was to compare tanker drivers' occupational exposure level before and after the installation of vapour recovery facilities at 14 service stations. Road tanker drivers are exposed when handling volatile petrol liquid in bulk in the distribution chain. The drivers' exposure was studied during the unloading operation as the bulk petrol flowed into underground storage tanks, displacing vapours in the tank space and causing emission to the environment and the drivers' work area. The exposures were measured again when the dual point Stage I vapour recovery systems were installed for recycling vapours. Short-term measurements were carried out in the drivers' breathing zones by drawing polluted air through a charcoal tube during unloading. The samples were analysed in the laboratory by gas chromatography for C3-C11 aliphatic hydrocarbons, tert-butyl methyl ether (MTBE), tert-amyl methyl ether (MTAE), benzene, toluene and xylene. The road tanker loads delivered consisted of oxygenated and reformulated petrol (E95 and E98 brands), which contained on average 13% oxygenates. Before the installation of the vapour recovery system, the geometric mean (GM) concentration of aliphatic hydrocarbons was 65 mg m-3 (range 6-645 mg m-3) in the drivers' breathing zones. After the installation at the same service stations, the corresponding exposure level was 8.3 mg m-3 (range < 1-79 mg m-3). The GM of the MTBE concentrations was 8.6 mg m-3 (range 1-67 mg m-3) without vapour recovery and 1.5 mg m-3 (range < 0.1-10 mg m-3) with vapour recovery. The differences between the aliphatic hydrocarbons and the MTBE exposure levels during the unloading of the road tankers without and with vapour recovery were statistically significant (p < 0.05).
本研究的目的是比较14个服务站安装油气回收设施前后油罐车司机的职业暴露水平。公路油罐车司机在配送链中大量处理挥发性汽油液体时会接触到有害物质。在卸载操作过程中,当大量汽油流入地下储油罐时,油罐空间中的蒸汽被置换出来,从而向环境和司机工作区域排放污染物,此时对司机的暴露情况进行了研究。当安装了双点一级油气回收系统以回收蒸汽时,再次对暴露情况进行了测量。在卸载过程中,通过将污染空气吸入活性炭管,在司机的呼吸区域进行短期测量。样品在实验室通过气相色谱法分析C3 - C11脂肪族烃、叔丁基甲基醚(MTBE)、叔戊基甲基醚(MTAE)、苯、甲苯和二甲苯。公路油罐车运送的货物包括含氧和重新配方的汽油(E95和E98品牌),平均含氧量为13%。在安装油气回收系统之前,司机呼吸区域中脂肪族烃的几何平均(GM)浓度为65毫克/立方米(范围为6 - 645毫克/立方米)。在同一服务站安装后,相应的暴露水平为8.3毫克/立方米(范围为<1 - 79毫克/立方米)。无油气回收时MTBE浓度的GM为8.6毫克/立方米(范围为1 - 67毫克/立方米),有油气回收时为1.5毫克/立方米(范围为<0.1 - 10毫克/立方米)。公路油罐车卸载过程中,有无油气回收时脂肪族烃和MTBE暴露水平的差异具有统计学意义(p < 0.05)。