甲亚胺叶立德的催化不对称1,3-偶极环加成反应——一种合成光学活性高官能化脯氨酸衍生物的简单方法。 - Suppr

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超能文献

Catalytic asymmetric 1,3-dipolar cycloaddition reactions of azomethine ylides-a simple approach to optically active highly functionalized proline derivatives.

作者信息

Gothelf Aase Sejr, Gothelf Kurt V, Hazell Rita G, Jørgensen Karl Anker

机构信息

Danish National Research Foundation: Center for Catalysis, Department of Chemistry, Aarhus University, Denmark.

出版信息

Angew Chem Int Ed Engl. 2002 Nov 15;41(22):4236-8. doi: 10.1002/1521-3773(20021115)41:22<4236::AID-ANIE4236>3.0.CO;2-W.

DOI:10.1002/1521-3773(20021115)41:22<4236::AID-ANIE4236>3.0.CO;2-W

PMID:12434349

Abstract

摘要

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Catalytic asymmetric 1,3-dipolar cycloaddition reactions of azomethine ylides-a simple approach to optically active highly functionalized proline derivatives.甲亚胺叶立德的催化不对称1,3-偶极环加成反应——一种合成光学活性高官能化脯氨酸衍生物的简单方法。

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Catalytic enantioselective 1,3-dipolar cycloaddition reaction of azomethine ylides and alkenes: the direct strategy to prepare enantioenriched highly substituted proline derivatives.甲亚胺叶立德与烯烃的催化对映选择性1,3-偶极环加成反应：制备对映体富集的高取代脯氨酸衍生物的直接策略。

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