Dai Hongjie
Department of Chemistry, Stanford University, Stanford, California 94305, USA.
Acc Chem Res. 2002 Dec;35(12):1035-44. doi: 10.1021/ar0101640.
Synthesis of carbon nanotubes by chemical vapor deposition over patterned catalyst arrays leads to nanotubes grown from specific sites on surfaces. The growth directions of the nanotubes can be controlled by van der Waals self-assembly forces and applied electric fields. The patterned growth approach is feasible with discrete catalytic nanoparticles and scalable on large wafers for massive arrays of novel nanowires. Controlled synthesis of nanotubes opens up exciting opportunities in nanoscience and nanotechnology, including electrical, mechanical, and electromechanical properties and devices, chemical functionalization, surface chemistry and photochemistry, molecular sensors, and interfacing with soft biological systems.
通过在图案化催化剂阵列上进行化学气相沉积来合成碳纳米管,可使纳米管从表面的特定位置生长。纳米管的生长方向可通过范德华自组装力和外加电场来控制。这种图案化生长方法对于离散的催化纳米颗粒是可行的,并且能够在大尺寸晶圆上进行扩展,以制备大量新型纳米线阵列。纳米管的可控合成在纳米科学和纳米技术领域开启了令人兴奋的机遇,包括电学、力学和机电性能及器件、化学功能化、表面化学和光化学、分子传感器以及与柔软生物系统的接口。