通过闭环复分解反应合成分枝杆菌内酯核心结构。
Synthesis of the mycolactone core by ring-closing metathesis.
作者信息
Alexander Matthew D, Fontaine Shaun D, La Clair James J, Dipasquale Antonio G, Rheingold Arnold L, Burkart Michael D
机构信息
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093-0358, USA.
出版信息
Chem Commun (Camb). 2006 Nov 28(44):4602-4. doi: 10.1039/b609408b. Epub 2006 Sep 21.
DOI:10.1039/b609408b
PMID:17082856
Abstract
The undecenolide core of mycolactone was synthesized by ring-closing metathesis and the structure confirmed using single-crystal X-ray diffraction techniques.
摘要
通过关环复分解反应合成了分枝杆菌内酯的十一碳烯内酯核心结构，并采用单晶X射线衍射技术对其结构进行了确认。
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