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具有碳纳米管阳极的有机发光二极管。

Organic light-emitting diodes having carbon nanotube anodes.

作者信息

Li Jianfeng, Hu Liangbing, Wang Lian, Zhou Yangxin, Grüner George, Marks Tobin J

机构信息

Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113, USA.

出版信息

Nano Lett. 2006 Nov;6(11):2472-7. doi: 10.1021/nl061616a.

DOI:10.1021/nl061616a
PMID:17090076
Abstract

Single-walled carbon nanotube (SWNT) films on flexible PET (polyethyleneterephthalate) substrates are used as transparent, flexible anodes for organic light-emitting diodes (OLEDs). For polymer-based OLEDs having the structure: SWNT/PEDOT-PSS:MeOH/TFB (poly(9,9-dioctylfluorene-co-N-(4-butylphenyl)diphenylamine)) + TPD-Si(2) (4,4'-bis[(p-trichlorosilylpropylphenyl)phenylamino]biphenyl) /BT (poly(9,9-dioctylfluorene-co-benzothiadiazole))/CsF/Al, a maximum light output of 3500 cd/m(2) and a current efficiency of 1.6 cd/A have been achieved. The device operational lifetime is comparable to that of devices with Sn-doped In(2)O(3) (ITO)/PET anodes. The advantages of this novel type of anode over conventional ITO are discussed.

摘要

柔性聚对苯二甲酸乙二酯(PET)基板上的单壁碳纳米管(SWNT)薄膜被用作有机发光二极管(OLED)的透明柔性阳极。对于具有以下结构的聚合物基OLED:SWNT/聚(3,4-乙撑二氧噻吩)-聚苯乙烯磺酸盐:甲醇/TFB(聚(9,9-二辛基芴-co-N-(4-丁基苯基)二苯胺))+TPD-Si(2)(4,4'-双[(对三氯硅烷基丙基苯基)苯基氨基]联苯)/BT(聚(9,9-二辛基芴-co-苯并噻二唑))/氟化铯/铝,已实现最大光输出为3500 cd/m²,电流效率为1.6 cd/A。该器件的工作寿命与具有掺锡氧化铟(ITO)/PET阳极的器件相当。讨论了这种新型阳极相对于传统ITO的优点。

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