Scott Elinor, Peter Francisc, Sanders Johan
Department of Valorisation of Plant Production Chains, Wageningen University, PO Box 17, 6700 AA Wageningen, The Netherlands.
Appl Microbiol Biotechnol. 2007 Jun;75(4):751-62. doi: 10.1007/s00253-007-0932-x. Epub 2007 Mar 27.
The depletion in fossil feedstocks, increasing oil prices, and the ecological problems associated with CO2 emissions are forcing the development of alternative resources for energy, transport fuels, and chemicals: the replacement of fossil resources with CO2 neutral biomass. Allied with this, the conversion of crude oil products utilizes primary products (ethylene, etc.) and their conversion to either materials or (functional) chemicals with the aid of co-reagents such as ammonia and various process steps to introduce functionalities such as -NH2 into the simple structures of the primary products. Conversely, many products found in biomass often contain functionalities. Therefore, it is attractive to exploit this to bypass the use, and preparation of, co-reagents as well as eliminating various process steps by utilizing suitable biomass-based precursors for the production of chemicals. It is the aim of this mini-review to describe the scope of the possibilities to generate current functionalized chemical materials using amino acids from biomass instead of fossil resources, thereby taking advantage of the biomass structure in a more efficient way than solely utilizing biomass for the production of fuels or electricity.
化石原料的枯竭、油价上涨以及与二氧化碳排放相关的生态问题,正促使人们开发能源、运输燃料和化学品的替代资源:用二氧化碳中性生物质替代化石资源。与此相关的是,原油产品的转化利用初级产品(如乙烯等),并借助氨等共试剂以及各种工艺步骤,将初级产品转化为材料或(功能性)化学品,以便将诸如-NH2等官能团引入初级产品的简单结构中。相反,生物质中发现的许多产品通常含有官能团。因此,利用这一点来绕过共试剂的使用和制备,并通过使用合适的生物质基前体来生产化学品,从而消除各种工艺步骤,是很有吸引力的。本微型综述的目的是描述利用生物质中的氨基酸而非化石资源来生成当前功能化化学材料的可能性范围,从而比单纯利用生物质生产燃料或电力更有效地利用生物质结构。