钯催化芳基（氮杂芳基）甲烷与芳基卤化物直接芳基化反应制备三芳基甲烷。
Palladium-catalyzed direct arylation of aryl(azaaryl)methanes with aryl halides providing triarylmethanes.
作者信息
Niwa Takashi, Yorimitsu Hideki, Oshima Koichiro
机构信息
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
出版信息
Org Lett. 2007 Jun 7;9(12):2373-5. doi: 10.1021/ol0708119. Epub 2007 May 12.
PMID:17497870
Abstract
Direct arylation of aryl(azaaryl)methanes with aryl halides takes place at the benzylic position in the presence of a hydroxide base under palladium catalysis to yield triarylmethanes.
摘要
在钯催化下，在氢氧化物碱存在的情况下，芳基（氮杂芳基）甲烷与芳基卤化物在苄基位置发生直接芳基化反应，生成三芳基甲烷。
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