IPy2BF4介导的正戊烯基糖苷向糖基氟化物的转化：一对新的半正交糖基供体。
IPy2BF4-mediated transformation of n-pentenyl glycosides to glycosyl fluorides: a new pair of semiorthogonal glycosyl donors.
作者信息
López J Cristóbal, Uriel Clara, Guillamón-Martín Alejandra, Valverde Serafín, Gómez Ana M
机构信息
Instituto de Química OrgAnica General CSIC, Madrid, Spain.
出版信息
Org Lett. 2007 Jul 19;9(15):2759-62. doi: 10.1021/ol070753r. Epub 2007 Jun 20.
PMID:17580878
Abstract
Bis(pyridinium) iodonium(I) tetrafluoroborate (IPy2BF4), a solid and stable reagent, can be used to transform n-pentenyl orthoesters (NPOEs) and n-pentenyl glycosides (NPGs) into glycosyl fluorides. The latter pair constitutes a new set of semiorthogonal glycosyl donors that can be used in glycosylation strategies, alone or in combination with NPOEs.
摘要
双（吡啶鎓）碘鎓（I）四氟硼酸盐（IPy2BF4）是一种固体且稳定的试剂，可用于将正戊烯基原酸酯（NPOEs）和正戊烯基糖苷（NPGs）转化为糖基氟化物。后一对化合物构成了一组新的半正交糖基供体，可单独或与NPOEs组合用于糖基化策略中。
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