铁盐在催化合成5-取代-1H-四唑中的应用
Iron salts in the catalyzed synthesis of 5-substituted 1H-tetrazoles.
作者信息
Bonnamour Julien, Bolm Carsten
机构信息
Institute for Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany.
出版信息
Chemistry. 2009;15(18):4543-5. doi: 10.1002/chem.200900169.
PMID:19296482
Abstract
Clicking iron: Cheap and environmentally friendly [Fe(OAc)(2)] is used for the catalysis of cycloadditions between aryl nitriles and trimethylsilyl azide to prepare substituted 1H-tetrazoles in good yield (see scheme).
摘要
点击铁
廉价且环保的[Fe(OAc)₂]用于催化芳基腈与三甲基硅基叠氮化物之间的环加成反应，以高收率制备取代的1H-四唑（见方案）。
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