3S-氟脯氨酸作为一种通过19F-核磁共振监测蛋白质折叠过程中脯氨酸异构化的探针。
3S-fluoroproline as a probe to monitor proline isomerization during protein folding by 19F-NMR.
作者信息
Thomas Colin A, Talaty Erach R, Bann James G
机构信息
Department of Chemistry, Wichita State University, Wichita, KS 67260-0051, USA.
出版信息
Chem Commun (Camb). 2009 Jun 21(23):3366-8. doi: 10.1039/b821952d. Epub 2009 May 19.
Abstract
Variable-temperature inversion transfer NMR is used to determine the kinetic and thermodynamic parameters of cis-trans isomerization of N-Ac-(3R) and (3S)-fluoroproline-OMe.
摘要
变温反转转移核磁共振用于测定N-乙酰基-(3R)和(3S)-氟脯氨酸甲酯顺反异构化的动力学和热力学参数。
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