β-三氟硼酸钾酰胺在铃木-宫浦交叉偶联反应中的应用。
Use of potassium beta-trifluoroborato amides in Suzuki-Miyaura cross-coupling reactions.
作者信息
Molander Gary A, Jean-Gérard Ludivine
机构信息
Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, USA.
出版信息
J Org Chem. 2009 Aug 7;74(15):5446-50. doi: 10.1021/jo900968h.
Abstract
Potassium beta-trifluoroborato amides were prepared and used as successful partners in Suzuki-Miyaura reactions with various aryl chlorides, including electron-rich and electron-poor derivatives, as well as several heteroaryl chloride partners.
摘要
制备了β-三氟硼酸钾酰胺，并将其用作与各种芳基氯（包括富电子和缺电子衍生物）以及几种杂芳基氯衍生物进行铃木-宫浦反应的成功搭档。
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