铜催化胺化反应高效合成氨基吡啶衍生物。
Efficient synthesis of aminopyridine derivatives by copper catalyzed amination reactions.
机构信息
UMR 6226-CNRS-Université de Rennes 1, Sciences Chimiques de Rennes, Catalyse et Organométalliques, Campus de Beaulieu, avenue du général Leclerc, 35042 Rennes cedex, France.
出版信息
Chem Commun (Camb). 2010 Feb 14;46(6):925-7. doi: 10.1039/b916569j. Epub 2009 Dec 7.
DOI:10.1039/b916569j
PMID:20107652
Abstract
A copper(i) catalyzed amination reaction utilizing aqueous ammonia and operating under mild conditions is presented. This method was employed for the efficient synthesis of various aminopyridine derivatives bearing electron withdrawing and electron donating groups.
摘要
本文提出了一种在温和条件下利用水合氨进行的铜（I）催化胺化反应。该方法可用于高效合成带有吸电子和供电子基团的各种氨基吡啶衍生物。
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