过渡金属催化的芳基羟基化合成。

Transition-metal-catalyzed synthesis of hydroxylated arenes.

机构信息

Organic Chemistry Department and Institute for Organic Synthesis (ISO), Universidad de Alicante, Carretera de San Vicente s/n, Apdo. 99, 03080, Alicante, Spain.

出版信息

Chemistry. 2010 May 10;16(18):5274-84. doi: 10.1002/chem.201000470.

DOI:10.1002/chem.201000470

PMID:20397168

Abstract

An overview of the recent bibliography in the transition-metal-catalyzed hydroxylation of aryl derivatives is presented. Two reaction protocols are considered: 1) C--H activation/hydroxylation and, 2) cross-coupling hydroxylation of aryl halides. The achievements and limitations for both procedures are described taking into consideration different metal catalyst/oxidant combinations.

摘要

呈现了近期过渡金属催化芳基衍生物羟化反应的文献综述。考虑了两种反应方案：1）C-H 活化/羟化，和 2）芳基卤化物的交叉偶联羟化。描述了这两种方法的成就和局限性，同时考虑了不同的金属催化剂/氧化剂组合。