Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, USA.
Org Lett. 2010 Jun 18;12(12):2848-51. doi: 10.1021/ol1009575.
Evaluation of the scope of a Pd(II)-catalyzed oxidative 1,1-diarylation reaction of terminal olefins using aryl stannanes is reported. The reaction is shown to be tolerant of functionality commonly encountered in organic synthesis; however, the reaction outcome was found to be dependent on the nature of the aryl stannane used. A mechanistic rationale for the observation of this influence is provided.
报道了使用芳基锡烷评估 Pd(II)催化末端烯烃的氧化 1,1-二芳基化反应范围。该反应对有机合成中常见的官能团具有耐受性；然而，反应结果发现取决于所使用的芳基锡烷的性质。为观察到这种影响提供了一种机理原理。
