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中国南方电子废物回收区和工业区土壤中十氯酮的含量和立体异构体分布。

Levels and isomer profiles of Dechlorane Plus in the surface soils from e-waste recycling areas and industrial areas in South China.

机构信息

State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China.

出版信息

Environ Pollut. 2010 Sep;158(9):2920-5. doi: 10.1016/j.envpol.2010.06.003. Epub 2010 Jul 13.

DOI:10.1016/j.envpol.2010.06.003
PMID:20630636
Abstract

Dechlorane Plus (DP) is a highly chlorinated flame retardant. Levels of DP were measured in surface soils from e-waste recycling areas and industrial areas in South China. Higher DP levels were found in e-waste recycling areas (undetectable-47.4 ng/g) than those in industrial areas (0.0336-4.65 ng/g) in South China. The highest DP concentration (3327 ng/g) was found at the e-waste recycling site in Qingyuan, while DP levels fell dramatically with increasing distance away from the recycling site, suggesting that the e-waste recycling activities are an important source of DP emissions. The mean ratios of anti-DP to total DP (fanti) for different sampling areas ranged from 0.58 to 0.76 and showed no significant difference from the ratio for the technical DP products (t-test, p>0.05). Further intensive studies are needed to investigate the process of DP degradation and its degradation products.

摘要

得克隆(DP)是一种高度氯化的阻燃剂。本研究在华南地区的电子废物回收区和工业区采集了表层土壤样本,并对其中 DP 的含量进行了检测。结果表明,电子废物回收区 DP 的含量(未检出-47.4ng/g)高于工业区(0.0336-4.65ng/g)。在清远的电子废物回收场地发现了 DP 的最高浓度(3327ng/g),且 DP 浓度随着与回收场地距离的增加而显著降低,表明电子废物的回收活动是 DP 排放的重要来源。不同采样区反式-DP 与总 DP 的平均比值(fanti)范围为 0.58-0.76,与技术 DP 产品的比值无显著差异(t 检验,p>0.05)。需要进一步进行深入研究,以调查 DP 的降解过程及其降解产物。

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