Ynamides: a modern functional group for the new millennium.
作者信息
DeKorver Kyle A, Li Hongyan, Lohse Andrew G, Hayashi Ryuji, Lu Zhenjie, Zhang Yu, Hsung Richard P
机构信息
Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53705, USA.
出版信息
Chem Rev. 2010 Sep 8;110(9):5064-106. doi: 10.1021/cr100003s.
Abstract
摘要
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本文引用的文献
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N-Functionalized 1-Alkynylamides: New Building Blocks for Transition Metal Mediated Inter- and Intramolecular [2+2+1] Cycloadditions.N-官能化的1-炔基酰胺：过渡金属介导的分子间和分子内[2+2+1]环加成反应的新型构建模块。
Angew Chem Int Ed Engl. 1998 Mar 2;37(4):489-492. doi: 10.1002/(SICI)1521-3773(19980302)37:4<489::AID-ANIE489>3.0.CO;2-N.
2
[2+2] Cycloaddition of ketenes with ynamides. A general method for the synthesis of 3-aminocyclobutenone derivatives.烯酮与烯炔酰胺的[2+2]环加成反应。一种合成3-氨基环丁烯酮衍生物的通用方法。
Tetrahedron. 2006 Apr 17;62(16):3815-3822. doi: 10.1016/j.tet.2005.11.088.
3
A unique approach to aldol products for the creation of all-carbon quaternary stereocentres.一种独特的方法用于合成全碳季碳立体中心的 aldol 产物。
Nat Chem. 2009 May;1(2):128-32. doi: 10.1038/nchem.131. Epub 2009 Mar 29.
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Synthesis and molecular properties of donor-pi-spacer-acceptor ynamides with up to four conjugated alkyne units.具有多达四个共轭炔烃单元的给体-π-间隔基-受体炔酰胺的合成与分子性质。
Chem Commun (Camb). 2010 May 7;46(17):2953-5. doi: 10.1039/b919275a. Epub 2010 Mar 8.
6
A divergent mechanistic course of Pd(0)-catalyzed aza-Claisen rearrangement and aza-Rautenstrauch-type cyclization of N-allyl ynamides.钯（0）催化的 N-烯丙基炔酰胺的氮杂-Claisen 重排和氮杂-Rautenstrauch 型环化的分歧机制途径。
Org Lett. 2010 Apr 16;12(8):1840-3. doi: 10.1021/ol100446p.
7
A Rhodium(I)-Xylyl-BINAP Catalyzed Asymmetric Ynamide-[2 + 2 + 2] Cycloaddition in the Synthesis of Optically Enriched N,O-Biaryls.铑（I）-二甲苯基-联萘酚膦催化的不对称烯酰胺-[2 + 2 + 2]环加成反应用于合成光学富集的N，O-二芳基化合物。
Tetrahedron. 2009 Jun 27;65(26):5001-5012. doi: 10.1016/j.tet.2009.03.078.
8
Cu-catalyzed N-alkynylation of imidazoles, benzimidazoles, indazoles, and pyrazoles using PEG as solvent medium.铜催化的咪唑、苯并咪唑、吲唑和吡唑的 N-炔基化反应，使用 PEG 作为溶剂介质。
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Nickel-catalyzed [3 + 2 + 2] cycloaddition of ethyl cyclopropylideneacetate and heteroatom-substituted alkynes: application to selective three-component reaction with 1,3-diynes.镍催化的乙基环丙叉基乙酸酯与杂原子取代炔烃的[3 + 2 + 2]环加成反应：在与 1,3-二炔的选择性三组分反应中的应用。
J Org Chem. 2010 Jan 15;75(2):480-3. doi: 10.1021/jo902251m.
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Synthesis of ketene N,N-acetals by copper-catalyzed double-amidation of 1,1-dibromo-1-alkenes.通过铜催化1,1-二溴-1-烯烃的双酰胺化反应合成乙烯酮N,N-缩醛
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