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Total Synthesis of (-)-Glionitrin A and B Enabled by an Asymmetric Oxidative Sulfenylation of Triketopiperazines.
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Catalytic enantioselective construction of vicinal quaternary carbon stereocenters.
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N-Heterocyclization in Gliotoxin Biosynthesis is Catalyzed by a Distinct Cytochrome P450 Monooxygenase.
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→π* Interactions Modulate the Disulfide Reduction Potential of Epidithiodiketopiperazines.
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A Three-Step Entry to the Aspirochlorine Family of Antifungal Agents.
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Total synthesis of (+)-11,11'-dideoxyverticillin A.
Science. 2009 Apr 10;324(5924):238-41. doi: 10.1126/science.1170777.
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Concise total synthesis of (+)-WIN 64821 and (-)-ditryptophenaline.
Angew Chem Int Ed Engl. 2008;47(8):1485-7. doi: 10.1002/anie.200704960.
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Construction of epidithiodioxopiperazines by directed oxidation of hydroxyproline-derived dioxopiperazines.
Org Lett. 2007 Dec 6;9(25):5267-70. doi: 10.1021/ol702518t. Epub 2007 Nov 15.
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Concise total synthesis of (-)-calycanthine, (+)-chimonanthine, and (+)-folicanthine.
Angew Chem Int Ed Engl. 2007;46(20):3725-8. doi: 10.1002/anie.200700705.
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Chaetocin: a promising new antimyeloma agent with in vitro and in vivo activity mediated via imposition of oxidative stress.
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