Davenport Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.
Org Lett. 2010 Nov 19;12(22):5186-8. doi: 10.1021/ol1019037. Epub 2010 Oct 15.
A palladium-catalyzed crossed biaryl coupling/reduction sequence enables the formation of meta-substituted biaryls via solvent-mediated arylpalladium(II) reduction. Isotope labeling studies determined that the decomposition of 1,2-dimethoxyethane (DME) is indeed involved in the reductive process.
钯催化的交叉联芳偶联/还原序列通过溶剂介导的芳基钯(II)还原实现了间位取代联芳基的形成。同位素标记研究表明，1,2-二甲氧基乙烷（DME）的分解确实参与了还原过程。
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