迈向环保实验室：机械合成金属有机化合物中的维度和反应性。
Towards an environmentally-friendly laboratory: dimensionality and reactivity in the mechanosynthesis of metal-organic compounds.
机构信息
Laboratory for Physical-Organic Chemistry, Division of Organic Chemistry and Biochemistry, Rudjer Bošković Institute, 10002 Zagreb, Croatia.
出版信息
Chem Commun (Camb). 2010 Dec 28;46(48):9191-3. doi: 10.1039/c0cc03822a. Epub 2010 Nov 8.
We present a proof-of-principle study of an environmentally-friendly approach to laboratory research, in which the synthesis and structural characterisation of metal-organic complexes and frameworks are achieved without using bulk solvents; our study addresses the use of heteroditopic ligands for manipulating the dimensionality of metal-organic materials and describes how kinetic obstacles in such mechanosynthesis can be overcome.
我们提出了一项环保型实验室研究方法的原理验证研究，其中无需使用大量溶剂即可实现金属有机配合物和框架的合成和结构表征；我们的研究探讨了杂双齿配体在控制金属有机材料维度方面的应用，并描述了如何克服这种机械合成中的动力学障碍。
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