钯催化的末端烯烃 1,1-芳氧基化反应。
Palladium-catalyzed 1,1-aryloxygenation of terminal olefins.
机构信息
University of Michigan, Department of Chemistry, Ann Arbor, Michigan 48109-1055, USA.
出版信息
Org Lett. 2011 Mar 4;13(5):1076-9. doi: 10.1021/ol103121r. Epub 2011 Feb 3.
Abstract
This paper describes the 1,1-arylacetoxylation of diverse α-olefins using organostannanes and hypervalent iodine oxidants. The reaction provides a convergent approach for generating a C-C and a C-O bond as well as a new stereocenter in a single catalytic transformation.
摘要
本文描述了使用有机锡烷和高价碘氧化剂对各种α-烯烃的 1,1-芳基乙氧羰基化反应。该反应提供了一种在单个催化转化中生成 C-C 和 C-O 键以及新的立体中心的收敛方法。
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