从小花无距耧斗菜地上部分分离得到的三种新黄酮碳苷。
Three new flavone C-glycosides from the aerial parts of Paraquilegia microphylla.
作者信息
Xu Kai-Jie, Xu Xue-Min, Deng Wen-Long, Zhang Lei, Wang Ming-Kui, Ding Li-Sheng
机构信息
Key Laboratory of Mountain Ecological Restoration and Bioresource Utilization, Chengdu Institute of Biology, Chinese Academy of Sciences, China.
出版信息
J Asian Nat Prod Res. 2011 May;13(5):409-16. doi: 10.1080/10286020.2011.568413.
Three new flavone C-glycosides, paraquinins A-C, were isolated from the aerial parts of Paraquilegia microphylla (Royle) Dromm. et Hutch, a Tibetan medicine distributed in the Qinghai-Tibet plateau. On the basis of 1D and 2D NMR evidence, their structures were elucidated as acacetin-6-C-β-D-glucopyranosyl-(1 → 2)-β-D-glucopyranoside (1), acacetin-6-C-α-L-rhamnopyranosyl-(1 → 2)-β-D-glucopyranosyl-(1 → 2)-β-D-glucopyranoside (2), and acacetin-6-C-α-L-rhamnopyranosyl-(1 → 2)-(6'''-O-E-feruloyl)-β-D-glucopyranosyl-(1 → 2)-β-D-glucopyranoside (3).
从分布于青藏高原的藏药小花假耧斗菜（Paraquilegia microphylla (Royle) Dromm. et Hutch）的地上部分分离得到了三种新的黄酮碳苷，即对叶百部宁A - C。基于一维和二维核磁共振证据，确定它们的结构分别为刺槐素 - 6 - C - β - D - 吡喃葡萄糖基 - (1→2) - β - D - 吡喃葡萄糖苷（1）、刺槐素 - 6 - C - α - L - 鼠李吡喃糖基 - (1→2) - β - D - 吡喃葡萄糖基 - (1→2) - β - D - 吡喃葡萄糖苷（2）和刺槐素 - 6 - C - α - L - 鼠李吡喃糖基 - (1→2) - (6''' - O - E - 阿魏酰基) - β - D - 吡喃葡萄糖基 - (1→2) - β - D - 吡喃葡萄糖苷（3）。
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