Schumers Jean-Marc, Fustin Charles-André, Gohy Jean-François
Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain, Place L. Pasteur, 1, Louvain-la-Neuve, Belgium.
Macromol Rapid Commun. 2010 Sep 15;31(18):1588-607. doi: 10.1002/marc.201000108. Epub 2010 May 20.
Stimuli-responsive polymers are the subject of intense research because they are able to show responses to various environmental changes. Among those stimuli, light has attracted much attention since it can be localized in time and space and it can also be triggered from outside of the system. In this paper, we review light-responsive block copolymers (LRBCs) that combine characteristic features of block copolymers, e.g., self-assembly behavior, and light-responsive systems. The different photo-responsive moieties that have been incorporated so far in block copolymers as well as the proposed applications are discussed.
刺激响应性聚合物是深入研究的主题，因为它们能够对各种环境变化做出响应。在这些刺激因素中，光因其可以在时间和空间上进行定位，并且还可以从系统外部触发而备受关注。在本文中，我们综述了兼具嵌段共聚物特征（例如自组装行为）和光响应系统的光响应性嵌段共聚物（LRBCs）。讨论了迄今为止已引入到嵌段共聚物中的不同光响应基团以及所提出的应用。
