二氯（2-吡啶胺）汞（II）
Dichlorido(di-2-pyridylamine)mercury(II).
作者信息
Yousefi Mohammad, Allahgholi Ghasri Mohammad Reza, Heidari Amene, Amani Vahid
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 6;65(Pt 1):m9-m10. doi: 10.1107/S1600536808040294.
In the mol-ecule of the title compound, [HgCl(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Cl atoms. In the crystal structure, inter-molecular N-H⋯Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers. There is a π-π contact between the pyridine rings [centroid-centroid distance = 3.896 (5) Å].
在标题化合物[HgCl₂(C₁₀H₉N₃)]的分子中，Hg(II)原子通过螯合二-2-吡啶胺配体的两个N原子和两个Cl原子以扭曲的四面体构型进行四配位。在晶体结构中，分子间的N-H⋯Cl氢键将分子连接成中心对称的二聚体。吡啶环之间存在π-π接触[质心-质心距离 = 3.896 (5) Å]。
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