• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

（E）-4-羟基-N'-（2-羟基-4-甲氧基亚苄基）苯甲酰肼一水合物

(E)-4-Hydr-oxy-N'-(2-hydr-oxy-4-methoxy-benzyl-idene)benzohydrazide monohydrate.

作者信息

Mohd Lair Nooraziah, Mohd Ali Hapipah, Ng Seik Weng

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 20;65(Pt 1):o189. doi: 10.1107/S1600536808042888.

DOI:10.1107/S1600536808042888
PMID:21581643
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968097/
Abstract

The Schiff base mol-ecule of the title compound, C(15)H(14)N(2)O(4)·H(2)O, adopts a trans configuration with respect to the C=N double bond; the Schiff base itself is almost planar (r.m.s. deviation for all non-H atoms = 0.040 Å). The amido N atom is the hydrogen-bond donor to the water mol-ecule, which is the hydrogen-bond donor to the hydr-oxy groups of two neighboring mol-ecules. One of the hydroxyl groups acts as an intra-molecular and the other as an inter-molecular hydrogen-bond donor.

摘要

标题化合物C(15)H(14)N(2)O(4)·H(2)O的席夫碱分子相对于C=N双键呈反式构型；席夫碱本身几乎是平面的（所有非H原子的均方根偏差 = 0.040 Å）。酰胺N原子是水分子的氢键供体，而水分子是两个相邻分子中羟基的氢键供体。其中一个羟基充当分子内氢键供体，另一个充当分子间氢键供体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3297/2968097/e12a50010899/e-65-0o189-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3297/2968097/e12a50010899/e-65-0o189-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3297/2968097/e12a50010899/e-65-0o189-fig1.jpg

相似文献

1
(E)-4-Hydr-oxy-N'-(2-hydr-oxy-4-methoxy-benzyl-idene)benzohydrazide monohydrate.（E）-4-羟基-N'-（2-羟基-4-甲氧基亚苄基）苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 20;65(Pt 1):o189. doi: 10.1107/S1600536808042888.
2
(E)-4-Hydr-oxy-N'-(2-hydr-oxy-4-methoxy-benzyl-idene)benzohydrazide N,N-dimethyl-formamide solvate.（E）-4-羟基-N'-（2-羟基-4-甲氧基苯亚甲基）苯甲酰肼 N，N-二甲基甲酰胺溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 20;65(Pt 1):o190. doi: 10.1107/S160053680804289X.
3
(E)-N'-(2-Hydr-oxy-4-methoxy-benzyl-idene)isonicotinohydrazide monohydrate.（E）-N'-（2-羟基-4-甲氧基-亚苄基）异烟酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 24;64(Pt 10):o1996-7. doi: 10.1107/S1600536808029619.
4
2-Hydr-oxy-N'-(2-hydr-oxy-4-methoxy-benzyl-idene)-3-methyl-benzohydrazide monohydrate.2-羟基-N'-(2-羟基-4-甲氧基亚苄基)-3-甲基苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 May 15;66(Pt 6):o1340. doi: 10.1107/S1600536810016855.
5
N'-(2-Hydr-oxy-4-methoxy-benzyl-idene)-4-methoxy-benzohydrazide.N'-(2-羟基-4-甲氧基-亚苄基)-4-甲氧基-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 22;65(Pt 9):o2200. doi: 10.1107/S1600536809032449.
6
N'-(4-Hydr-oxy-3-methoxy-benzyl-idene)acetohydrazide monohydrate.N'-(4-羟基-3-甲氧基-亚苄基)乙酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 26;65(Pt 10):o2514. doi: 10.1107/S1600536809037489.
7
N'-(3,5-Di-tert-butyl-4-hydroxy-benzyl-idene)-2-hydroxy-benzohydrazide methanol solvate.N'-(3,5-二叔丁基-4-羟基-亚苄基)-2-羟基苯甲酰肼甲醇溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 9;64(Pt 8):o1452. doi: 10.1107/S1600536808020746.
8
(E)-Methyl N'-(2-hydr-oxy-3-methoxy-benzyl-idene)hydrazinecarboxyl-ate.（E）-N'-（2-羟基-3-甲氧基苄叉基）肼基甲酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 10;65(Pt 7):o1548. doi: 10.1107/S1600536809021631.
9
(E)-N'-(2-Hydr-oxy-3,5-diiodo-benzyl-idene)-2-nitro-benzohydrazide methanol solvate.（E）-N'-（2-羟基-3,5-二碘苄叉基）-2-硝基苯甲酰肼甲醇溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 26;65(Pt 9):o2238. doi: 10.1107/S1600536809033091.
10
N'-(2-Hydr-oxy-3-methoxy-benzyl-idene)-1,3-benzodioxole-5-carbohydrazide monohydrate.N'-(2-羟基-3-甲氧基亚苄基)-1,3-苯并二恶唑-5-碳酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 6;65(Pt 1):o29. doi: 10.1107/S1600536808040117.

引用本文的文献

1
4-Meth-oxy-N'-(3-nitro-benzyl-idene)benzohydrazide.
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):o1725. doi: 10.1107/S1600536812020454. Epub 2012 May 16.
2
4-Hy-droxy-N'-(3-nitro-benzyl-idene)benzohydrazide.4-羟基-N'-(3-硝基亚苄基)苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1352. doi: 10.1107/S1600536812014778. Epub 2012 Apr 13.
3
4-Chloro-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide methanol monosolvate.4-氯-N'-(2-羟基-4-甲氧基亚苄基)苯甲酰肼甲醇单溶剂合物

本文引用的文献

1
2-Meth-oxy-N'-(2-methoxy-benzyl-idene)benzohydrazide.2-甲氧基-N'-(2-甲氧基亚苄基)苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1695. doi: 10.1107/S160053680802521X.
2
4-Chloro-N'-(2-hydroxy-benzyl-idene)benzohydrazide monohydrate.4-氯-N'-(2-羟基-亚苄基)苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1694. doi: 10.1107/S1600536808024471.
3
N'-(2-Hydroxy-benzyl-idene)-2-methoxy-benzohydrazide monohydrate.N'-(2-羟基-亚苄基)-2-甲氧基苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o2825. doi: 10.1107/S1600536811039778. Epub 2011 Oct 5.
4
Bis[4-hydr-oxy-N'-(4-meth-oxy-2-oxido-benzyl-idene-κO)benzohydrazidato-κO,N']cadmium(II) dimethyl sulfoxide disolvate.双[4-羟基-N'-(4-甲氧基-2-氧化苯亚甲基-κO)苯甲酰肼基-κO,N']镉(II)二甲亚砜溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):m541. doi: 10.1107/S1600536809013774.
5
(E)-3-Bromo-N'-(4-hydr-oxy-3-nitro-benzyl-idene)benzohydrazide.
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 1;65(Pt 8):o1725. doi: 10.1107/S1600536809024131.
6
4-Meth-oxy-N'-(2-methoxy-benzyl-idene)benzohydrazide.4-甲氧基-N'-(2-甲氧基亚苄基)苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 May 23;65(Pt 6):o1388. doi: 10.1107/S1600536809019102.
7
(E)-3-Bromo-N'-(2-chloro-benzyl-idene)benzohydrazide.（E）-3-溴-N'-（2-氯亚苄基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):o1705. doi: 10.1107/S160053680902412X.
8
(E)-3-Bromo-N'-(2-hydr-oxy-1-naphthyl-idene)benzohydrazide.（E）-3-溴-N'-（2-羟基-1-萘基亚甲基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 17;65(Pt 7):o1600. doi: 10.1107/S1600536809022533.
9
(E)-N'-(3,5-Dibromo-2-hydroxy-benzyl-idene)-2-methoxy-benzohydrazide.（E）-N'-（3,5-二溴-2-羟基-亚苄基）-2-甲氧基-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 17;65(Pt 7):o1587. doi: 10.1107/S1600536809022168.
10
N'-(5-Chloro-2-hydroxy-benzyl-idene)nicotinohydrazide.N'-(5-氯-2-羟基-亚苄基)烟酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):o1505-6. doi: 10.1107/S1600536809020819.
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1693. doi: 10.1107/S1600536808024483.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
5
Design, synthesis and in vitro antimalarial activity of an acylhydrazone library.酰腙文库的设计、合成及体外抗疟活性
Bioorg Med Chem Lett. 2006 Jan 1;16(1):31-5. doi: 10.1016/j.bmcl.2005.09.058. Epub 2005 Nov 2.