Norwegian Institute for Air Research (NILU), FRAM Centre, Hjalmar Johansens gate 14, NO-9296 Tromsø, Norway.
Chemosphere. 2011 Sep;84(11):1686-93. doi: 10.1016/j.chemosphere.2011.04.075. Epub 2011 May 31.
Polyfluorinated compounds (PFCs) are an extremely versatile class of compounds and are used in a variety of consumer applications and products. Recent studies have suggested that PFCs in indoor air and dust could act as sources of human exposure and outdoor air contamination. This study presents method development and analysis of a wide range of PFCs in dust and air using active sampling techniques with commercially available sampling equipment (forensic nozzles with filter housings for dust collection and polyurethane foam (PUF)-XAD(2)-PUF sandwich-tubes for air sampling) using both liquid and gas chromatography mass spectrometry. The developed method was validated and tested for applicability to analyze dust and air samples at both low and high concentrations (0.5 ng and 25 ng per analyte per air sample, respectively). Samples from private households and an office building were analyzed to explore differences in distribution patterns and concentrations. Perfluorooctane sulfonate, perfluorodecane sulfonate, perfluoroheptanoate, perfluorooctanoate and perfluorononanoate were observed in all samples of dust from private households, in the range from 1 to 80.1 ng g(-1). Fluorotelomer alcohols (FTOHs) were the predominant PFCs in indoor air samples with ∑FTOHs ranging between 4.7 and 17.9 ng m(-3). The concentrations found in the present study are generally lower than those previously reported. This variation may be due to differences associated with geographical locations and lifestyles. However, use of different sampling techniques and strategies among studies can introduce large variations in PFC concentration found, making direct comparisons challenging.
全氟化合物(PFCs)是一类用途广泛的化合物,广泛应用于各种消费产品和应用中。最近的研究表明,室内空气和灰尘中的 PFCs 可能成为人类暴露和室外空气污染的来源。本研究提出了一种使用商用采样设备(用于灰尘收集的法医喷嘴和用于空气采样的聚氨酯泡沫(PUF)-XAD(2)-PUF 夹心管)的活性采样技术,对灰尘和空气中的多种 PFCs 进行了方法开发和分析,使用液相色谱和气相色谱质谱法。该方法经过验证,并针对在低浓度(分别为每个空气样本中的每个分析物 0.5ng 和 25ng)和高浓度(分别为每个空气样本中的每个分析物 0.5ng 和 25ng)下分析灰尘和空气样品的适用性进行了测试。对来自私人住宅和办公大楼的样本进行了分析,以探讨分布模式和浓度的差异。全氟辛烷磺酸、全氟癸烷磺酸、全氟庚酸、全氟辛酸和全氟壬酸均在私人住宅灰尘的所有样本中被发现,浓度范围为 1 至 80.1ng/g。氟调聚物醇(FTOHs)是室内空气样本中主要的 PFCs,∑FTOHs 范围在 4.7 至 17.9ng/m3 之间。本研究中发现的浓度通常低于以前的报告。这种差异可能是由于地理位置和生活方式的不同造成的。然而,由于研究中使用的采样技术和策略不同,可能会导致 PFC 浓度存在很大差异,使得直接比较具有挑战性。