高选择性反应的无偏向烯基卤化物和烷基卤化锌：尼希希-普拉斯偶联。
Highly selective reactions of unbiased alkenyl halides and alkylzinc halides: Negishi-Plus couplings.
机构信息
Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, USA.
出版信息
Org Lett. 2011 Aug 5;13(15):3822-5. doi: 10.1021/ol201307y. Epub 2011 Jul 8.
Abstract
High yielding stereo- and chemoselective Pd-catalyzed cross-couplings in THF at room temperature of alkenyl iodides and bromides with primary and secondary alkyl zinc iodides have been developed with the aid of N-methyimidazole as the key additive.
摘要
在室温下，在 N-甲基咪唑作为关键添加剂的帮助下，开发了高产立体和化学选择性 Pd 催化的烯基碘化物和溴化物与伯和仲烷基锌碘化物的交叉偶联反应，在四氢呋喃中进行。
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