金催化的炔丙位取代反应：范围和合成进展。
Gold-catalyzed propargylic substitutions: Scope and synthetic developments.
机构信息
Institut Charles Gerhardt, UMR 5253, Equipe AM2N, ENSCM 8 rue de l'Ecole Normale, 34296 Montpellier Cédex, France.
出版信息
Beilstein J Org Chem. 2011;7:866-77. doi: 10.3762/bjoc.7.99. Epub 2011 Jun 28.
Abstract
This personal account summarizes our recent developments in gold-catalyzed direct substitutions on propargylic (allylic, benzylic) alcohols, with various nucleophiles (and bi-nucleophiles) based on the σ- and/or π-acidity of gold(III) complexes. Synthetic developments are also briefly described.
摘要
这篇个人述评总结了我们最近在金催化炔丙基（烯丙基、苄基）醇的直接取代反应方面的进展，涉及各种亲核试剂（和双亲核试剂），基于金(III)配合物的σ-和/或π-酸性。合成方面的发展也做了简要描述。
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