9-氮杂金刚烷氮氧化物（Nor-AZADO）：一种用于醇氧化的高活性有机催化剂。
9-Azanoradamantane N-oxyl (Nor-AZADO): a highly active organocatalyst for alcohol oxidation.
作者信息
Hayashi Masaki, Sasano Yusuke, Nagasawa Shota, Shibuya Masatoshi, Iwabuchi Yoshiharu
机构信息
Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Sendai, Japan.
出版信息
Chem Pharm Bull (Tokyo). 2011;59(12):1570-3. doi: 10.1248/cpb.59.1570.
PMID:22130384
Abstract
A highly active organocatalyst for alcohol oxidation has been developed. 9-Azanoradamantane N-oxyl (Nor-AZADO 4), constituting an unhindered, stable nitroxyl radical, exhibits superior catalytic activity to 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and AZADOs in the oxidation of alcohols to their corresponding carbonyl compounds.
摘要
一种用于醇氧化的高活性有机催化剂已被开发出来。9-氮杂金刚烷N-氧基（Nor-AZADO 4），构成一种无阻碍的稳定硝酰自由基，在将醇氧化为相应羰基化合物的反应中，表现出比2,2,6,6-四甲基哌啶-1-氧基（TEMPO）和AZADOs更优异的催化活性。
Zotero 插件