Fakultät für Chemie und Pharmazie, Ludwig-Maximilians-Universität München, and Munich Center of Integrated Protein Science, Butenandtstr. 5-13, 81377 München, Germany.
J Org Chem. 2012 Jul 6;77(13):5838-43. doi: 10.1021/jo300726z. Epub 2012 Jun 20.
A synthetic approach to several sesterterpenoids containing an isopropyl trans-hydrindane system is presented. Its most remarkable feature is the stereochemical diversification of a common precursor through the choice of different hydrogenation conditions.
本文提出了一种合成含有异丙基反-六氢茚烷系统的几种倍半萜的方法。其最显著的特点是通过选择不同的氢化条件,使一个共同的前体在立体化学上多样化。