Dibromido(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')(dimethyl sulfoxide-κO)cadmium.
作者信息
Shirvan Sadif A, Haydari Dezfuli Sara
机构信息
Department of Chemistry, Islamic Azad University, Omidieh Branch, Omidieh, Iran.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m1006-7. doi: 10.1107/S1600536812028553. Epub 2012 Jun 30.
Abstract
In the title compound, [CdBr(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal-bipyramidal geometry by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine (DMBP) ligand, one O atom from a dimethyl sulfoxide (DMSO) ligand and two Br atoms. A weak intra-molecular C-H⋯O hydrogen bond occurs between the DMBP and DMSO ligands. π-π stacking between pyridine rings [centroid-centroid distances = 3.682 (3) and 3.598 (3) Å] is observed in the crystal.
摘要
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