Trichlorido(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')(methanol-κO)indium(III) methanol monosolvate.
作者信息
Shirvan Sadif A, Haydari Dezfuli Sara
机构信息
Department of Chemistry, Islamic Azad University, Omidieh Branch, Omidieh, Iran.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1189-90. doi: 10.1107/S1600536812035490. Epub 2012 Aug 23.
Abstract
In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a methanol mol-ecule and three Cl atoms. In the crystal, inter-molecular O-H⋯O and O-H⋯Cl hydrogen bonds link the complex and solvent methanol mol-ecules. Intra-molecular C-H⋯Cl hydrogen bonds are also present in the complex.
摘要
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