催化中的氧化还原活性配体。
Redox-active ligands in catalysis.
机构信息
Yale Chemistry Dept. and Energy Sciences Institute, P.O. Box 208107, 225 Prospect St., New Haven, CT 06520-8107, USA.
出版信息
Chem Soc Rev. 2013 Feb 21;42(4):1440-59. doi: 10.1039/c2cs35228a. Epub 2012 Sep 13.
PMID:22975722
Abstract
Odd-electron, redox-active ligands are discussed in the context of catalysis. We focus on ligand-based, non-singlet state intermediates and their participation in catalytic processes and related stoichiometric transformations.
摘要
本文讨论了催化作用中的奇电子、氧化还原活性配体。我们专注于基于配体的非单重态中间体及其在催化过程和相关计量转化中的参与。
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