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同时测定李属樱属植物的果实、核仁及利口酒中的花色苷、香豆素和酚酸

Simultaneous determination of anthocyanins, coumarins and phenolic acids in fruits, kernels and liqueur of Prunus mahaleb L.

机构信息

Department of Pharmaceutical Sciences, University of Florence, via Ugo Schiff 6, 50019 Sesto Fiorentino (FI), Italy.

出版信息

Food Chem. 2012 Dec 15;135(4):2157-62. doi: 10.1016/j.foodchem.2012.07.083. Epub 2012 Jul 24.

DOI:10.1016/j.foodchem.2012.07.083
PMID:22980784
Abstract

In the fresh tissues of Prunus mahaleb L., three classes of phenolics were characterised: phenolic acid derivatives (main compound being o-coumaric acid glucoside), quercetin glycosides, and anthocyanins (cyanidin 3,5-diglucoside, cyanidin 3-sambubioside, cyanidin 3-xylosyl-rutinoside and cyanidin 3-rutinoside). Coumarin was also identified. The kernels showed a high content of coumarin (0.87 mgg(-1)) which is the main class of metabolites in this sample, but present in pitted berries as well (0.63 mgg(-1)). Flavonoids are mainly concentrated in the skin and pulp (0.55 mgg(-1)). In 'Mirinello di Torremaggiore' liqueur, produced from P. mahaleb L. in accordance with traditional procedures, anthocyanins make up 16.5%, phenolic acids 43.3%, coumarin 36.2% and flavonoids 4% of total compounds. Anthocyanins are the main class in solid residues from liqueur production (70%). These findings point out that solid residues of P. mahaleb can be considered an interesting and innovative source of appreciable amounts of cyanidin glycosides (3.3 mgg(-1)).

摘要

在李属樱桃的新鲜组织中,鉴定出了三类酚类物质:酚酸衍生物(主要化合物为对香豆酸葡萄糖苷)、槲皮苷和花色苷(矢车菊素 3,5-二葡萄糖苷、矢车菊素 3-桑布双糖苷、矢车菊素 3-木糖基芦丁糖苷和矢车菊素 3-芦丁糖苷)。此外,还鉴定出了香豆素。李属樱桃的仁中含有较高含量的香豆素(0.87 mgg(-1)),这是该样品中主要的代谢物类别,但李属樱桃核仁中也存在凹陷的浆果(0.63 mgg(-1))。类黄酮主要集中在果皮和果肉中(0.55 mgg(-1))。在按照传统工艺由李属樱桃制成的“Torremaggiore 甜酒”中,花色苷占 16.5%、酚酸占 43.3%、香豆素占 36.2%、类黄酮占 4%,占总化合物的比例。花色苷是甜酒生产固体残渣中的主要类别(70%)。这些发现表明,李属樱桃的固体残渣可以被视为一个有趣且创新的来源,可获得相当数量的矢车菊苷(3.3 mgg(-1))。

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