Aix Marseille Université, CNRS, LCE, FRE 3416, 13331 Marseille Cedex 03, France.
Environ Sci Pollut Res Int. 2013 Jul;20(7):4659-70. doi: 10.1007/s11356-012-1394-y. Epub 2013 Jan 4.
Volatile organic compounds (VOCs) and particles emitted by incense sticks and candles combustion in an experimental room have been monitored on-line and continuously with a high time resolution using a state-of-the-art high sensitivity-proton transfer reaction-mass spectrometer (HS-PTR-MS) and a condensation particle counter (CPC), respectively. The VOC concentration-time profiles, i.e., an increase up to a maximum concentration immediately after the burning period followed by a decrease which returns to the initial concentration levels, were strongly influenced by the ventilation and surface interactions. The obtained kinetic data set allows establishing a qualitative correlation between the elimination rate constants of VOCs and their physicochemical properties such as vapor pressure and molecular weight. The emission of particles increased dramatically during the combustion, up to 9.1(±0.2) × 10(4) and 22.0(±0.2) × 10(4) part cm(-3) for incenses and candles, respectively. The performed kinetic measurements highlight the temporal evolution of the exposure level and reveal the importance of ventilation and deposition to remove the particles in a few hours in indoor environments.
采用最先进的高灵敏度质子转移反应质谱仪(HS-PTR-MS)和凝结核计数器(CPC),在线连续地以高时间分辨率监测了实验室内香薰蜡烛燃烧时挥发的有机化合物(VOCs)和颗粒。VOC 浓度-时间曲线,即在燃烧期后立即上升到最大浓度,随后下降并回到初始浓度水平,强烈受到通风和表面相互作用的影响。获得的动力学数据集允许在 VOC 的消除率常数与其物理化学性质(如蒸气压和分子量)之间建立定性相关性。燃烧过程中,颗粒的排放量急剧增加,分别达到 9.1(±0.2)×10(4)和 22.0(±0.2)×10(4)个颗粒 cm(-3)。进行的动力学测量突出了暴露水平的时间演变,并揭示了通风和沉积在数小时内去除室内环境中颗粒的重要性。