二溴（2,9-二甲基-1,10-菲咯啉-κ(2) N,N'）（二甲基亚砜-κO）镉
Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N')(dimethyl sulfoxide-κO)cadmium.
作者信息
Moghanlou Khadijeh
机构信息
Department of Chemistry, North Tehran Branch, Islamic Azad University, Tehran, Iran.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m49. doi: 10.1107/S1600536812050106. Epub 2012 Dec 12.
In the mol-ecule of the title compound, [CdBr2(C14H12N2)(C2H6OS)], the Cd(II) atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. In the crystal, π-π contacts between the pyridine and benzene rings [centroid-centroid distances = 3.710 (5), 3.711 (6) and 3.627 (5) Å] stabilize the structure.
在标题化合物[CdBr₂(C₁₄H₁₂N₂)(C₂H₆OS)]的分子中，Cd(II)原子由一个2,9 - 二甲基 - 1,10 - 菲咯啉配体的两个N原子、一个二甲基亚砜配体的一个O原子和两个Br原子以扭曲的三角双锥构型进行五配位。在晶体中，吡啶环和苯环之间的π - π接触[质心 - 质心距离 = 3.710 (5)、3.711 (6)和3.627 (5) Å]使结构得以稳定。
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