利用佩里桉培养细胞对α-蒎烯和β-蒎烯进行区域选择性羟基化和糖基化反应
Regioselective hydroxylation and glucosylation of alpha- and beta-pinenes with cultured cells of Eucalyptus perriniana.
作者信息
Shimoda Kei, Kubota Naoji, Hamada Manabu, Suwada Ken, Hamada Hatsuyuki, Hamada Hiroki
机构信息
Department of Chemistry, Faculty of Medicine, Oita University, 1-1 Hasama-machi, Oita 879-5593, Japan.
出版信息
Nat Prod Commun. 2013 Jul;8(7):847-9.
PMID:23980409
Abstract
Cultured plant cells of Eucalyptus perriniana regioselectively hydroxylated (+)- and (-)-alpha-pinenes to the corresponding (+)- and (-)-verbenols. In addition, (+)- and (-)-verbenols were converted into mono-beta-D-glucosides. On the other hand, (+)- and (-)-beta-pinenes were transformed into (+)- and (-)-pinocarveol 3-O-beta-D-glucosides via (+)- and (-)-pinocarveols.
摘要
培林桉的培养植物细胞将（+）-和（-）-α-蒎烯区域选择性地羟基化为相应的（+）-和（-）-马鞭草烯醇。此外，（+）-和（-）-马鞭草烯醇被转化为单-β-D-葡萄糖苷。另一方面，（+）-和（-）-β-蒎烯通过（+）-和（-）-松樟醇转化为（+）-和（-）-松樟醇3-O-β-D-葡萄糖苷。
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