Department of Chemistry, Emory University , 1515 Dickey Drive, Atlanta, Georgia 30322, United States.
Org Lett. 2013 Dec 20;15(24):6152-4. doi: 10.1021/ol403017e. Epub 2013 Nov 14.
A silver-catalyzed vinylogous fluorination of vinyl diazoacetates to generate γ-fluoro-α,β-unsaturated carbonyls is presented. Application of this method to the fluorination of farnesol and steroid derivatives was achieved.
本文报道了一种银催化的乙烯基重氮乙酰胺的反式 vinylogous 氟化反应，生成了γ-氟-α,β-不饱和羰基化合物。该方法被应用于法呢醇和甾体衍生物的氟化反应中。
