无过渡金属的酸介导硫醇和硫醚合成芳基硫醚
Transition-metal-free acid-mediated synthesis of aryl sulfides from thiols and thioethers.
作者信息
Wagner Anna M, Sanford Melanie S
机构信息
Department of Chemistry, University of Michigan , 930 North University Avenue, Ann Arbor, Michigan 48109, United States.
出版信息
J Org Chem. 2014 Mar 7;79(5):2263-7. doi: 10.1021/jo402567b. Epub 2014 Feb 19.
PMID:24548014
Abstract
The preparation of diaryl and alkyl aryl sulfides via acid-mediated coupling of thiols and thioethers with diaryliodonium salts is reported. The scope, limitations, and mechanism of the transformation are discussed.
摘要
报道了通过硫醇和硫醚与二芳基碘鎓盐的酸介导偶联制备二芳基和烷基芳基硫化物的方法。讨论了该转化反应的范围、局限性及反应机理。
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