无过渡金属、可见光诱导芳基磺酰氯与2-异氰基联苯环化反应制备菲啶。
Transition-metal-free, visible-light induced cyclization of arylsulfonyl chlorides with 2-isocyanobiphenyls to produce phenanthridines.
作者信息
Gu Lijun, Jin Cheng, Liu Jiyan, Ding Hongyan, Fan Baomin
机构信息
Key Laboratory of Chemistry in Ethnic Medicinal Resources, State Ethnic Affairs Commission & Ministry of Education, Yunnan University of Nationalities, Kunming, Yunnan 650500, China.
出版信息
Chem Commun (Camb). 2014 May 7;50(35):4643-5. doi: 10.1039/c4cc01487a.
PMID:24671455
Abstract
6-Aryl substituted phenanthridines were synthesized via a visible-light-catalyzed cyclization of 2-isocyanobiphenyls with arylsulfonyl chlorides under oxidant-free and transition-metal-free conditions. This transformation represents an efficient and attractive synthetic utilization of arylsulfonyl chlorides.
摘要
通过在无氧化剂和无过渡金属的条件下，2-异氰基联苯与芳基磺酰氯的可见光催化环化反应合成了6-芳基取代菲啶。这种转化代表了芳基磺酰氯的一种高效且有吸引力的合成应用。
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