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监测西班牙中部地区自来水中的内分泌干扰化合物及雌激素活性。

Monitoring endocrine disrupting compounds and estrogenic activity in tap water from Central Spain.

作者信息

Esteban S, Gorga M, González-Alonso S, Petrovic M, Barceló D, Valcárcel Y

机构信息

Environmental Health and Ecotoxicology Research Group (ToxAmb), Rey Juan Carlos University, Avda. Atenas, s/n., 28922, Alcorcón, Madrid, Spain,

出版信息

Environ Sci Pollut Res Int. 2014;21(15):9297-310. doi: 10.1007/s11356-014-2847-2. Epub 2014 Apr 13.

Abstract

The aims of this study are to investigate the presence of 30 substances known or thought to act as endocrine disrupting compounds in tap water from the main water supply areas for region of Madrid, to determine the total estrogenic activity of the samples analysed and to estimate the health risk for the population resulting from those compounds found at detectable concentrations. To this end, a one-off composite sampling was performed in August 2012 in which six tap water samples were collected from private residences in the drinking water supply network of the region of Madrid. A total of 14 of the 30 endocrine disruptors analysed were found at concentrations ranging from 0.3 to 165 ng/L. The organophosphorus flame retardants were detected at the highest concentrations followed by the plasticizer bisphenol A, alkylphenols, anticorrosion agents and preservatives. Tap water in the region of Madrid is contaminated with traces (ng/L) of compounds with endocrine disrupting properties. Although the concentrations of endocrine disrupting compounds obtained are too low to be able to confirm a public health risk, and no risk has been detected upon evaluation, it should be remembered that these compounds act at very low doses and that their effects may only appear in the long term.

摘要

本研究的目的是调查马德里地区主要供水区域自来水中已知或被认为具有内分泌干扰特性的30种物质的存在情况,测定所分析样品的总雌激素活性,并评估检测到的这些化合物对人群造成的健康风险。为此,于2012年8月进行了一次性混合采样,从马德里地区饮用水供应网络中的私人住宅采集了6份自来水样本。在所分析的30种内分泌干扰物中,共有14种被检测到,浓度范围为0.3至165纳克/升。有机磷阻燃剂的检测浓度最高,其次是增塑剂双酚A、烷基酚、防腐剂和保鲜剂。马德里地区的自来水受到具有内分泌干扰特性的痕量(纳克/升)化合物的污染。尽管所获得的内分泌干扰化合物浓度过低,无法确认存在公共健康风险,且评估时未检测到风险,但应记住,这些化合物在极低剂量下起作用,其影响可能仅在长期内显现。

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