Thin Film Nano Tech. Lab., Department of Electronic Engineering, Chang Gung University, 259 Wen-Hwa 1st Rd., Kwei-Shan, Tao-Yuan 333, Taiwan.
Nanoscale Res Lett. 2014 Jun 10;9(1):292. doi: 10.1186/1556-276X-9-292. eCollection 2014.
Self-compliance resistive random access memory (RRAM) characteristics using a W/TaO x /TiN structure are reported for the first time. A high-resolution transmission electron microscope (HRTEM) image shows an amorphous TaO x layer with a thickness of 7 nm. A thin layer of TiO x N y with a thickness of 3 nm is formed at the TaO x /TiN interface, owing to the oxygen accumulation nature of Ti. This memory device shows 100 consecutive switching cycles with excellent uniformity, 100 randomly picked device-to-device good uniformity, and program/erase endurance of >10(3) cycles. It is observed that the 0.6-μm devices show better switching uniformity as compared to the 4-μm devices, which is due to the thinner tungsten (W) electrode as well as higher series resistance. The oxygen-rich TaO x layer at the W/TaO x interface also plays an important role in getting self-compliance resistive switching phenomena and non-linear current-voltage (I-V) curve at low resistance state (LRS). Switching mechanism is attributed to the formation and rupture of oxygen vacancy conducting path in the TaO x switching material. The memory device also exhibits long read endurance of >10(6) cycles. It is found that after 400,000 cycles, the high resistance state (HRS) is decreased, which may be due to some defects creation (or oxygen moves away) by frequent stress on the switching material. Good data retention of >10(4) s is also obtained.
首次报道了使用 W/TaO x /TiN 结构的自一致性电阻式随机存取存储器(RRAM)特性。高分辨率透射电子显微镜(HRTEM)图像显示出厚度为 7nm 的非晶 TaO x 层。由于 Ti 的氧积累性质,在 TaO x /TiN 界面形成了厚度为 3nm 的薄 TiO x N y 层。该存储器件具有 100 个连续的开关循环,具有出色的均匀性,100 个随机挑选的器件间良好的均匀性,以及>10(3)个循环的编程/擦除耐久性。观察到 0.6μm 器件的开关均匀性优于 4μm 器件,这是由于钨(W)电极更薄以及串联电阻更高。W/TaO x 界面处富氧 TaO x 层在获得自一致性电阻开关现象和低阻态(LRS)下的非线性电流-电压(I-V)曲线方面也起着重要作用。开关机制归因于 TaO x 开关材料中氧空位导电通道的形成和破裂。该存储器件还表现出>10(6)个周期的长读取耐久性。发现经过 400,000 个循环后,高阻态(HRS)降低,这可能是由于开关材料频繁受到应力作用而产生了一些缺陷(或氧的迁移)。还获得了>10(4)秒的良好数据保持力。